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Select the correct relationship among the concentrations of species present in a 1.0 M aqueous solution of the weak acid represented by HA.


A) [H2O] > [A-] ~ [H3O+] > [HA] > [OH-]
B) [H2O] > [HA] > [A-] > [H3O+] > [OH-]
C) [HA] > [H2O] > [A-] > [H3O+] > [OH-]
D) [H2O] > [HA] > [A-] ~ [H3O+] > [OH-]
E) [HA] > [H2O] > [A-] ~ [H3O+] > [OH-]

F) A) and E)
G) A) and B)

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It is not possible to have a pH lying outside the range 0 to 14.

A) True
B) False

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The ammonium ion, NH4+, is a weak acid.

A) True
B) False

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Calcium oxide, CaO, also known as quick lime, will react with carbon dioxide to form calcium carbonate, CaCO3. Which species, if any, acts as a Lewis acid in the reaction?


A) Ca2+
B) O2-
C) CO2
D) CaCO3
E) None of these choices are correct.

F) A) and B)
G) C) and D)

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Which, if any, of the following acids is strong?


A) phosphoric
B) carbonic
C) acetic
D) water
E) None of these choices are correct.

F) C) and E)
G) C) and D)

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The strongest base which can exist in water is the hydroxide ion.

A) True
B) False

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The substance Ba(OH) 2 is considered


A) a weak Arrhenius acid.
B) a weak Arrhenius base.
C) a strong Arrhenius acid.
D) a strong Arrhenius base.
E) a neutral compound.

F) A) and B)
G) A) and C)

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Which one of the following will give a solution with a pH > 7, but is not an Arrhenius base in the strict sense?


A) CH3NH2
B) NaOH
C) CO2
D) Ca(OH) 2
E) CH4

F) B) and E)
G) C) and E)

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Which of the following is the strongest acid?


A) CH3COOH
B) HF
C) H3PO4
D) H2SO3
E) H2SO4

F) All of the above
G) B) and D)

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A 1.25 M solution of the weak acid HA is 9.2% dissociated. What is the pH of the solution?


A) 0.64
B) 0.94
C) 1.13
D) 2.16
E) None of these choices are correct.

F) B) and D)
G) All of the above

Correct Answer

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Which of the following pairs has the stronger acid listed first?


A) H2AsO3, H2AsO4
B) HI, HBr
C) HClO, HClO3
D) H2S, HCl
E) H2SO3, H2SO4

F) B) and E)
G) D) and E)

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All strong acids have weak conjugate bases.

A) True
B) False

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Lactic acid has a pKa of 3.08. What is the approximate degree of dissociation of a 0.35 M solution of lactic acid?


A) 1.1%
B) 2.2%
C) 4.8%
D) 14%
E) None of these choices are correct.

F) A) and D)
G) A) and C)

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What is the pH of a 0.75 M HNO3 solution?


A) 0.12
B) 0.29
C) 0.63
D) 0.82
E) > 1.0

F) None of the above
G) A) and E)

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What is the pH of a 0.20 M HCl solution?


A) < 0
B) 0.70
C) 1.61
D) 12.39
E) 13.30

F) A) and E)
G) B) and E)

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An aqueous solution is prepared by dissolving the salt formed by the neutralization of a weak acid by a weak base. Which statement about the solution is correct?


A) The solution is strongly basic.
B) The solution is weakly basic.
C) The solution is neutral.
D) The solution is acidic.
E) The values for Ka and Kb for the species in solution must be known before a prediction can be made.

F) A) and E)
G) D) and E)

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Kw = 1.0 × 10-14, regardless of temperature.

A) True
B) False

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Hydrated metal ions in aqueous solution can act as Brønsted-Lowry acids.

A) True
B) False

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Aqueous solutions of phosphoric acid and sodium nitrite are combined, and the following equilibrium is established. H3PO4(aq) + NO2(aq) Aqueous solutions of phosphoric acid and sodium nitrite are combined, and the following equilibrium is established. H<sub>3</sub>PO<sub>4</sub>(aq)  + NO<sub>2</sub>(aq)    H<sub>2</sub>PO<sub>4</sub>(aq)  + HNO<sub>2</sub>(aq)  The equilibrium constant K<sub>c</sub> for this reaction is greater than one. Based on this information, which of the following statements is correct? A)  Phosphoric acid is a weaker acid than nitrous acid. B)  Nitrous acid is a weaker acid than water. C)  The nitrite anion is a weaker base than the dihydrogen phosphate anion. D)  The dihydrogen phosphate anion is a stronger acid than nitrous acid. E)  Phosphoric acid is a stronger acid than nitrous acid. H2PO4(aq) + HNO2(aq) The equilibrium constant Kc for this reaction is greater than one. Based on this information, which of the following statements is correct?


A) Phosphoric acid is a weaker acid than nitrous acid.
B) Nitrous acid is a weaker acid than water.
C) The nitrite anion is a weaker base than the dihydrogen phosphate anion.
D) The dihydrogen phosphate anion is a stronger acid than nitrous acid.
E) Phosphoric acid is a stronger acid than nitrous acid.

F) None of the above
G) B) and D)

Correct Answer

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Which one of the following pairs is not a conjugate acid-base pair?


A) H2O/OH-
B) H2O2/HO2-
C) OH-/O2-
D) H2PO4-/HPO42-
E) HCl/H+

F) A) and E)
G) B) and E)

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