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For a chemical reaction to be spontaneous only at high temperatures, which of the following conditions must be met?


A) ( Δ\Delta S °\degree > 0, Δ\Delta H °\degree > 0)
B) ( Δ\Delta S °\degree > 0, Δ\Delta H °\degree < 0)
C) ( Δ\Delta S °\degree < 0, Δ\Delta H °\degree < 0)
D) ( Δ\Delta S °\degree < 0, Δ\Delta H °\degree > 0)
E) ( Δ\Delta G °\degree > 0)

F) D) and E)
G) All of the above

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Given: H2O(l) \rightarrow H2O(g) , Δ\Delta H °\degree = 40.7 kJ at 373K, what is the entropy change in the system ( Δ\Delta S) when one mole of water vaporizes at 100 °\degree C and a pressure of one atmosphere?


A) 407 J/K
B) -407 J/K
C) 109 J/K
D) -109 J/K
E) J/K

F) A) and B)
G) None of the above

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In which one of these pairs will the entropy of the first substance be greater than that of the second? Assume P and T are the same for each pair, unless stated otherwise.


A) 1 mole of F2(g) ; 1 mole of Cl2(g)
B) 1 mole of I2(s) ; 1 mole of I2(g)
C) 1 mole of CaCO3(s) ; 1 mole of CaO(s) plus 1 mole of CO2(g)
D) 1 mole of H2(g) at 25 °\degree C; 1 mole of H2(g) at 50 °\degree C
E) 1 mole of O3(g) ; 1 mole of O2(g)

F) All of the above
G) A) and E)

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Consider the reaction  Consider the reaction   If the concentrations of the Cu<sup>+</sup> and I¯ ions in equilibrium at 298 K are both equal to 1.03 *10¯<sup>6</sup> M, what is the value of  \Delta G \degree for the reaction? A)  -68 kJ B)  68 kJ C)  -30. kJ D)  30 kJ E)  34 kJ If the concentrations of the Cu+ and I¯ ions in equilibrium at 298 K are both equal to 1.03 *10¯6 M, what is the value of Δ\Delta G °\degree for the reaction?


A) -68 kJ
B) 68 kJ
C) -30. kJ
D) 30 kJ
E) 34 kJ

F) A) and D)
G) A) and B)

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Which of the following pairs has the member with the greater molar entropy listed first? All systems are at 25 °\degree C.


A) CO(g) , CO2(g)
B) NaCl(s) , NaCl(aq)
C) H2S(g) , H2S(aq)
D) Li(s) , Pb(s)
E) H2(g) , H2O(g)

F) A) and B)
G) B) and E)

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