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Hydroxylamine, HONH2, readily forms salts such as hydroxylamine hydrochloride which are used as antioxidants in soaps. Hydroxylamine has Kb of 9.1 * 10¯9. What is the pH of a 0.025 M HONH2 solution?


A) 2.90
B) 4.82
C) 9.18
D) 9.91
E) 11.10

F) A) and B)
G) All of the above

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Which of the following acids has the lowest pH?


A) 0.1 M HBO, pKa = 2.43
B) 0.1 M HA, pKa = 4.55
C) 0.1 M HMO, pKa = 8.23
D) 0.1 M HST, pKa = 11.89
E) pure water

F) A) and D)
G) None of the above

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If the compound HX is a strong acid (where H is the acidic proton in this acid), then the ion X¯ is a weak base.

A) True
B) False

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What is the [OH¯] for a solution at 25 °\degree C that has [H3O+] = 8.23 *10¯2 M?


A) > 10¯5 M
B) 1.22 * 10¯6 M
C) 8.23 *10¯12 M
D) 1.22 * 10¯13 M
E) 8.23 * 10¯16 M

F) All of the above
G) B) and D)

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Given:  Given:   When the temperature of a sample of pure water is raised above 25  \degree C, A)  the hydronium ion concentration will be greater than the hydroxide ion concentration. B)  the hydronium ion concentration will be less than the hydroxide ion concentration. C)  the value of K<sub>w</sub> will increase. D)  the hydronium ion concentration could change to 1.0 *10¯<sup>10</sup> M. E)  the hydroxide ion concentration could change to 1.0 *10¯<sup>10</sup> M. When the temperature of a sample of pure water is raised above 25 °\degree C,


A) the hydronium ion concentration will be greater than the hydroxide ion concentration.
B) the hydronium ion concentration will be less than the hydroxide ion concentration.
C) the value of Kw will increase.
D) the hydronium ion concentration could change to 1.0 *10¯10 M.
E) the hydroxide ion concentration could change to 1.0 *10¯10 M.

F) D) and E)
G) B) and E)

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The English are fond of soggy French fries ("chips") wrapped in old newspaper and generously drenched in vinegar, which is a 0.83 M solution of acetic acid. If the acetic acid in vinegar is 0.47% dissociated, calculate Ka for this acid.

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Ka = 1.8 *10¯5

What is the pH of a 0.010 M triethanolammonium chloride, (HOC2H2) 3NHCl, solution? Kb, ((HOC2H2) 3N) = 5.9 *10¯7


A) 2.75
B) 4.89
C) 9.11
D) 11.25
E) None of these choices is correct.

F) A) and D)
G) A) and C)

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B

If a strong acid such as HCl is diluted sufficiently with water, the pH will be higher than 7.

A) True
B) False

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Which of the following aqueous systems has the highest pH?


A) 0.1 M HA, pKa = 11.89
B) 0.1 M HMO, pKa = 8.23
C) 0.1 M HA, pKa = 4.55
D) 0.1 M HBO, pKa = 2.43
E) pure water

F) A) and C)
G) C) and D)

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What is the [OH¯] for a solution at 25 °\degree C that has [H3O+] = 2.35 * 10¯3 M?


A) 4.26 * 10¯5 M
B) 2.35 *10¯11 M
C) 4.26 * 10¯12 M
D) 2.35 *10¯17 M
E) None of these choices is correct.

F) C) and D)
G) A) and C)

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A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution. The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants. Which of the statements about the equilibrium system is correct? A student adds 0.1 mol of oxalic acid and 0.1 mol of sodium dihydrogen phosphate to enough water to make 1.0 L of solution. The following equilibrium is established with the concentrations of the products greater than the concentrations of the reactants. Which of the statements about the equilibrium system is correct?   A)  Oxalic acid is a weaker acid than phosphoric acid. B)  The hydrogen oxalate anion, HC<sub>2</sub>O<sub>4</sub>¯, is a stronger base than the dihydrogen phosphate anion, H<sub>2</sub>PO<sub>4</sub>¯. C)  Phosphoric acid is a weaker acid than oxalic acid. D)  The dihydrogen phosphate anion, H<sub>2</sub>PO<sub>4</sub>¯, is a stronger acid than oxalic acid. E)  Water is a stronger acid than either oxalic or phosphoric acids.


A) Oxalic acid is a weaker acid than phosphoric acid.
B) The hydrogen oxalate anion, HC2O4¯, is a stronger base than the dihydrogen phosphate anion, H2PO4¯.
C) Phosphoric acid is a weaker acid than oxalic acid.
D) The dihydrogen phosphate anion, H2PO4¯, is a stronger acid than oxalic acid.
E) Water is a stronger acid than either oxalic or phosphoric acids.

F) C) and E)
G) A) and E)

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All Brønsted-Lowry bases contain the hydroxide ion, OH¯.

A) True
B) False

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What is the value of Kb for the formate anion, HCOO¯? Ka(HCOOH) = 2.1 * 10¯4


A) -2.1 * 10¯4
B) 2.1 * 10¯4
C) 6.9 * 10¯6
D) 4.8 * 10¯11
E) 2.1 *10¯18

F) A) and B)
G) C) and D)

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A) Write a balanced equation representing the reaction of the acid, H2PO4¯ with the base, water. B) Write the expression for Ka of H2PO4¯ in terms of concentrations of relevant species.

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A)11ec9252_d986_1849_b435_a90f...

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The substance HClO4 is considered


A) a weak acid.
B) a weak base.
C) a strong acid.
D) a strong base.
E) a neutral compound.

F) D) and E)
G) C) and D)

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C

Picric acid has been used in the leather industry and in etching copper. However, its laboratory use has been restricted because it dehydrates on standing and can become shock sensitive. It has an acid dissociation constant of 0.42. What is the [H3O+] for a 0.20 M solution of picric acid?


A) 0.022 M
B) 0.052 M
C) 0.15 M
D) 0.29 M
E) None of these choices is correct.

F) C) and E)
G) A) and B)

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The substance (CH3CH2) 2NH is considered


A) a weak acid.
B) a weak base.
C) a strong acid.
D) a strong base.
E) a neutral compound.

F) None of the above
G) A) and C)

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The hydrated Al3+ ion, Al(H2O) 63+, is a weak acid in water. What are the products of its reaction with H2O? Al(H2O) 63+(aq) + H2O(l) \rightarrow ?


A) Al(H2O) 5OH2+(aq) + H3O+(aq)
B) Al(H2O) 6H4+(aq) + OH¯( aq)
C) Al(H2O) 53+(aq) + 2H2O(l)
D) Al(H2O) 6OH2+(aq) + H3O+( aq)
E) Al(H2O) 62+(aq) + H3O+( aq)

F) A) and B)
G) A) and C)

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A solution is prepared by adding 0.10 mol of iron(III) nitrate, Fe(NO3) 3, to 1.00 L of water. Which statement about the solution is correct?


A) The solution is basic.
B) The solution is neutral.
C) The solution is acidic.
D) The value of Ka for the species in solution must be known before a prediction can be made.
E) The value of Kb for the species in solution must be known before a prediction can be made.

F) C) and E)
G) A) and C)

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Ammonium chloride is used as an electrolyte in dry cells. Which of the following statements about a 0.10 M solution of NH4Cl, is correct?


A) The solution is weakly basic.
B) The solution is strongly basic.
C) The solution is neutral.
D) The solution is acidic.
E) The values for Ka and Kb for the species in solution must be known before a prediction can be made.

F) B) and E)
G) B) and D)

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