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According to the VSEPR model, a molecule with the general formula AB5 with no lone pairs on the central atom will have a ________ molecular geometry.


A) tetrahedral
B) trigonal planar
C) trigonal pyramidal
D) trigonal bipyramidal
E) seesaw

F) A) and B)
G) All of the above

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In not more than two sentences, explain when and why chemists make use of the concept of hybridization.

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Chemists postulate hybridizati...

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According to molecular orbital theory, what is the bond order in the O2+ ion?


A) 5.5
B) 5
C) 4
D) 2.5
E) 1.5

F) A) and B)
G) A) and C)

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Which is the most reasonable prediction for the three F-Br-F bond angles in BrF3?


A) 90°, 90°, and 180°
B) 86°, 94°, and 180°
C) 86°, 86°, and 172°
D) 94°, 94°, and 172°
E) 120°, 120°, and 120°

F) All of the above
G) A) and B)

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The number of lone pairs on the central atom is used to determine the ________.

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For a homonuclear diatomic molecule, which molecular orbital is the highest in energy?


A) For a homonuclear diatomic molecule, which molecular orbital is the highest in energy? A)    B)    C)    D)    E)  All of these orbitals have the same energy.
B) For a homonuclear diatomic molecule, which molecular orbital is the highest in energy? A)    B)    C)    D)    E)  All of these orbitals have the same energy.
C) For a homonuclear diatomic molecule, which molecular orbital is the highest in energy? A)    B)    C)    D)    E)  All of these orbitals have the same energy.
D) For a homonuclear diatomic molecule, which molecular orbital is the highest in energy? A)    B)    C)    D)    E)  All of these orbitals have the same energy.
E) All of these orbitals have the same energy.

F) A) and B)
G) A) and E)

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Using the VSEPR model, what is the predicted molecular geometry of the PCl3 molecule?


A) linear
B) bent
C) trigonal planar
D) trigonal pyramidal
E) tetrahedral

F) A) and B)
G) A) and C)

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How many electron domains are on the central atom for a sp3d hybridized atom?

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According to valence bond theory, the triple bond in ethyne (acetylene, C2H2) consists of


A) three σ bonds and no According to valence bond theory, the triple bond in ethyne (acetylene, C<sub>2</sub>H<sub>2</sub>)  consists of A)  three σ bonds and no   bonds. B)  two σ bonds and one   bond. C)  one σ bond and two   bonds. D)  no σ bonds and three   bonds. E)  one σ bond, one   bond, and one bond intermediate between σ and   . bonds.
B) two σ bonds and one According to valence bond theory, the triple bond in ethyne (acetylene, C<sub>2</sub>H<sub>2</sub>)  consists of A)  three σ bonds and no   bonds. B)  two σ bonds and one   bond. C)  one σ bond and two   bonds. D)  no σ bonds and three   bonds. E)  one σ bond, one   bond, and one bond intermediate between σ and   . bond.
C) one σ bond and two According to valence bond theory, the triple bond in ethyne (acetylene, C<sub>2</sub>H<sub>2</sub>)  consists of A)  three σ bonds and no   bonds. B)  two σ bonds and one   bond. C)  one σ bond and two   bonds. D)  no σ bonds and three   bonds. E)  one σ bond, one   bond, and one bond intermediate between σ and   . bonds.
D) no σ bonds and three According to valence bond theory, the triple bond in ethyne (acetylene, C<sub>2</sub>H<sub>2</sub>)  consists of A)  three σ bonds and no   bonds. B)  two σ bonds and one   bond. C)  one σ bond and two   bonds. D)  no σ bonds and three   bonds. E)  one σ bond, one   bond, and one bond intermediate between σ and   . bonds.
E) one σ bond, one According to valence bond theory, the triple bond in ethyne (acetylene, C<sub>2</sub>H<sub>2</sub>)  consists of A)  three σ bonds and no   bonds. B)  two σ bonds and one   bond. C)  one σ bond and two   bonds. D)  no σ bonds and three   bonds. E)  one σ bond, one   bond, and one bond intermediate between σ and   . bond, and one bond intermediate between σ and According to valence bond theory, the triple bond in ethyne (acetylene, C<sub>2</sub>H<sub>2</sub>)  consists of A)  three σ bonds and no   bonds. B)  two σ bonds and one   bond. C)  one σ bond and two   bonds. D)  no σ bonds and three   bonds. E)  one σ bond, one   bond, and one bond intermediate between σ and   . .

F) A) and D)
G) A) and C)

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What is the bond order for the species O2?


A) 1
B) 1.5
C) 2
D) 2.5
E) None of these choices.

F) C) and E)
G) A) and B)

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Which one of the following molecules is polar?


A) PBr5
B) CCl4
C) BrF5
D) XeF2
E) XeF4

F) A) and B)
G) A) and E)

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According to molecular orbital theory, all diatomic molecules with an even number of electrons are diamagnetic.

A) True
B) False

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Which figure best illustrates the hybrid orbitals on iodine in ICl2-?


A) Which figure best illustrates the hybrid orbitals on iodine in ICl<sub>2</sub><sup>-</sup>? A)    B)    C)    D)    E)
B) Which figure best illustrates the hybrid orbitals on iodine in ICl<sub>2</sub><sup>-</sup>? A)    B)    C)    D)    E)
C) Which figure best illustrates the hybrid orbitals on iodine in ICl<sub>2</sub><sup>-</sup>? A)    B)    C)    D)    E)
D) Which figure best illustrates the hybrid orbitals on iodine in ICl<sub>2</sub><sup>-</sup>? A)    B)    C)    D)    E)
E) Which figure best illustrates the hybrid orbitals on iodine in ICl<sub>2</sub><sup>-</sup>? A)    B)    C)    D)    E)

F) A) and B)
G) A) and E)

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How many bonds are there in one molecule of acrylonitrile (shown below) ? How many bonds are there in one molecule of acrylonitrile (shown below) ?   A)  1 B)  2 C)  3 D)  5 E)  9


A) 1
B) 2
C) 3
D) 5
E) 9

F) B) and D)
G) B) and C)

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Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl5?


A) Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl<sub>5</sub>? A)    B)    C)    D)    E)
B) Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl<sub>5</sub>? A)    B)    C)    D)    E)
C) Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl<sub>5</sub>? A)    B)    C)    D)    E)
D) Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl<sub>5</sub>? A)    B)    C)    D)    E)
E) Which is the correct hybrid orbital diagram representing the hybridization of iodine in ICl<sub>5</sub>? A)    B)    C)    D)    E)

F) All of the above
G) A) and B)

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Which one of the following molecules is polar?


A) CH4
B) CHBr3
C) F2
D) CBr4
E) CO2

F) B) and C)
G) All of the above

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Which one of the following molecules has a zero dipole moment?


A) CO
B) CH2Cl2
C) SO3
D) SO2
E) NH3

F) All of the above
G) A) and B)

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Which is true concerning the dipole moment of a CO2 molecule?


A) The dipole moment is zero because the C-O bond is nonpolar.
B) The dipole moment is zero because the molecule is linear.
C) The dipole moment is zero because the molecule is bent.
D) The dipole moment is nonzero because the molecule is linear.
E) The dipole moment is nonzero because the molecule is bent.

F) A) and B)
G) A) and C)

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For a polyatomic ion having the general formula AB3n±, where A is an atom from Group 6A, B is an atom from Group 7A, and the ionic charge is n±, what charge must the ion have in order to yield a molecular geometry that is trigonal pyramidal?


A) 3-
B) 1-
C) 1+
D) 3+
E) 5+

F) C) and D)
G) A) and C)

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According to the VSEPR model, the predicted molecular geometry of ammonia, NH3, is


A) linear.
B) trigonal planar.
C) bent.
D) tetrahedral.
E) trigonal pyramidal.

F) A) and B)
G) A) and E)

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