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In which one of the following species is the central atom (the first atom in the formula) likely to violate the octet rule?


A) BF4
B) XeO3
C) SiCl4
D) NH3
E) CH2Cl2

F) All of the above
G) C) and D)

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What is the number of lone electron pairs on the central atom of a molecule having a linear molecular geometry, such as CO2?


A) 1
B) 2
C) 3
D) 0
E) 4

F) D) and E)
G) A) and E)

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Helium atoms do not combine to form He2 molecules, yet He atoms do attract one another weakly through


A) dipole-dipole forces.
B) ion-dipole forces.
C) dispersion forces.
D) dipole-induced dipole forces.
E) hydrogen bonding.

F) B) and E)
G) B) and D)

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The total number of lone pairs in NCl3 is


A) 6.
B) 8.
C) 9.
D) 10.
E) 13.

F) B) and D)
G) None of the above

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Which is the most reasonable prediction for the H-O-H bond angle in H2O?


A) 90°
B) 109.5°
C) 120°
D) 107°
E) 105°

F) A) and E)
G) A) and D)

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The number of resonance structures for the sulfur dioxide molecule that satisfy the octet rule is


A) 1.
B) 2.
C) 3.
D) 4.
E) none of these

F) A) and C)
G) B) and C)

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Which pair of Lewis structures is not a pair of resonance structures?


A) Which pair of Lewis structures is not a pair of resonance structures?  A)    B)    C)   D) All of these pairs are resonance structures of the same species. E) None of these pairs is resonance structures of the same species.
B) Which pair of Lewis structures is not a pair of resonance structures?  A)    B)    C)   D) All of these pairs are resonance structures of the same species. E) None of these pairs is resonance structures of the same species.
C) Which pair of Lewis structures is not a pair of resonance structures?  A)    B)    C)   D) All of these pairs are resonance structures of the same species. E) None of these pairs is resonance structures of the same species.
D) All of these pairs are resonance structures of the same species.
E) None of these pairs is resonance structures of the same species.

F) B) and E)
G) B) and C)

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What is the molecular geometry of the thiocyanate anion, SCN, as predicted by the VSEPR model? (Carbon is the central atom.)


A) linear
B) bent
C) tetrahedral
D) trigonal planar
E) trigonal pyramidal

F) B) and D)
G) All of the above

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According to the VSEPR model, a molecule with the general formula AB3 with no lone pairs on the central atom will have a ______ molecular shape.


A) linear
B) bent
C) trigonal planar
D) tetrahedral
E) trigonal pyramidal

F) A) and E)
G) A) and D)

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According to the VSEPR model, which molecule is predicted to be linear?


A) H2S
B) HCN
C) BF3
D) H2CO
E) SO3

F) A) and B)
G) A) and C)

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Which of these choices is the best Lewis structure for ozone, O3?


A) Which of these choices is the best Lewis structure for ozone, O<sub>3</sub>? A)    B)    C)    D)    E)
B) Which of these choices is the best Lewis structure for ozone, O<sub>3</sub>? A)    B)    C)    D)    E)
C) Which of these choices is the best Lewis structure for ozone, O<sub>3</sub>? A)    B)    C)    D)    E)
D) Which of these choices is the best Lewis structure for ozone, O<sub>3</sub>? A)    B)    C)    D)    E)
E) Which of these choices is the best Lewis structure for ozone, O<sub>3</sub>? A)    B)    C)    D)    E)

F) A) and D)
G) A) and E)

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According to the VSEPR model, what is the predicted Cl-C-Cl bond angle in CCl4?


A) 90°
B) 109.5°
C) 120°
D) 145°
E) 180°

F) A) and D)
G) A) and E)

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The total number of bonding electrons in a molecule of formaldehyde (H2CO) is


A) 3.
B) 4.
C) 6.
D) 8.
E) 18.

F) B) and C)
G) All of the above

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According to the VSEPR model, the molecular geometry of the carbonate ion, CO32−, is


A) square planar.
B) tetrahedral.
C) pyramidal.
D) trigonal planar.
E) octahedral.

F) A) and B)
G) A) and C)

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Ammonia's unusually high melting point is the result of


A) dipole-dipole forces.
B) London dispersion forces.
C) hydrogen bonding.
D) covalent bonding.
E) ionic bonding.

F) B) and E)
G) None of the above

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How many lone pairs of electrons need to be added to complete this Lewis structure? How many lone pairs of electrons need to be added to complete this Lewis structure?   A) 5 B) 10 C) 0 D) 1 E) 6


A) 5
B) 10
C) 0
D) 1
E) 6

F) B) and E)
G) A) and C)

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How many total resonance structures can be drawn for the sulfate ion, SO42−?


A) 2
B) 3
C) 4
D) 5
E) 6

F) C) and D)
G) A) and D)

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Place the following in order of increasing electronegativity. N As K Ca


A) K < Ca < N < As
B) N < As < Ca < K
C) As < Ca < K < N
D) N < K < Ca < As
E) K < Ca < As < N

F) C) and E)
G) B) and E)

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The Lewis structure for a chlorate ion, ClO3-, should show ____ single bond(s) , ____ double bond(s) , and ____ lone pair(s) .


A) 2, 1, 10
B) 3, 0, 9
C) 2, 1, 8
D) 3, 0, 10
E) 2, 1, 9

F) B) and D)
G) A) and C)

Correct Answer

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Predict the molecular geometry and polarity of the CS2 molecule.


A) linear, polar
B) linear, nonpolar
C) tetrahedral, nonpolar
D) bent, nonpolar
E) bent, polar

F) C) and D)
G) A) and B)

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