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For the electrochemical cell Ni(s) | Ni2+(1 M) || H+(1 M) | H2(1 atm) | Pt(s) , which one of the following changes will cause a decrease in the cell voltage?


A) Increase the pressure of H2 to 2.0 atm.
B) Decrease the mass of the nickel electrode.
C) Lower the pH of the cell electrolyte.
D) Decrease the concentration of Ni2+ ion.
E) None of the above.

F) A) and E)
G) B) and C)

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Which of these metals will not reduce water to hydrogen in basic solution under standard conditions?


A) Cd
B) Sr
C) Mg
D) Ba
E) K

F) A) and B)
G) A) and C)

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Calculate the minimum voltage required for the electrolysis of 1.0 M NaCl in neutral solution. 2H2O + 2Cl- (1.0 M) \rarr H2(1 atm) + Cl2(1 atm) + 2OH- (1 * 10-7 M)


A) 2.19 V
B) 1.78 V
C) 0.41 V
D) -0.41 V
E) -1.78 V

F) C) and D)
G) B) and E)

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Which of these metals will reduce water to hydrogen in basic solution under standard conditions?


A) Pb
B) Fe
C) Zn
D) Na
E) Ag

F) C) and D)
G) A) and E)

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The overall reaction 2Co3+(aq) + 2Cl-(aq) \rarr 2Co2+(aq) + Cl2(g) has the standard cell voltage E°cell = 0.46 V. Given E° = 1.36 V for the reaction Cl2(g) + 2e- \rarr 2Cl-(aq) , calculate the standard reduction potential for the following the half reaction at 25°C: Co3+ + e- \rarr Co2+


A) 1.82 V
B) -0.90 V
C) 0.90 V
D) -1.82 V
E) -1.36 V

F) A) and D)
G) B) and C)

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Consider an electrochemical cell based on the spontaneous reaction 2AgCl(s) + Zn(s) \rarr 2Ag(s) + 2Cl- + Zn2+. If the zinc ion concentration is kept constant at 1 M, and the chlorine ion concentration is decreased from 1 M to 0.001 M, the cell voltage should


A) increase by 0.06 V.
B) increase by 0.18 V.
C) decrease by 0.06 V.
D) decrease by 0.18 V.
E) increase by 0.35 V.

F) B) and D)
G) A) and B)

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Complete and balance the following redox equation using the set of smallest whole-numbers coefficients. What is the sum of the coefficients? HI + HNO3 \rarr I2 + NO (acidic solution)


A) 5
B) 7
C) 14
D) 17
E) None of these.

F) B) and D)
G) A) and D)

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Consider an electrochemical cell with the following cell reaction where all reactants and products are at standard-state conditions: Cu2+(aq) + H2(g) \rarr Cu(s) + 2H+(aq) . Predict the effect on the emf of this cell of adding NaOH solution to the hydrogen half-cell until the pH equals 7.0.


A) The emf will increase.
B) The emf will decrease.
C) No change in the emf will be observed.

D) None of the above
E) All of the above

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When a solution of a certain gadolinium salt is electrolyzed with a current of 1.0 A for 2.0 h, 0.025 mol of Gd metal forms. Calculate the charge on the gadolinium ion in the salt.

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Determine the equilibrium constant (Keq) at 25°C for the reaction Cl2(g) + 2Br- (aq) \rarr 2Cl- (aq) + Br2(l)


A) 1.5 * 10-10
B) 6.3 * 109
C) 1.3 * 1041
D) 8.1 * 104
E) 9.8

F) A) and B)
G) None of the above

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Given the following notation for an electrochemical cell Pt(s) | H2(g) | H+(aq) || Ag+(aq) | Ag(s) What is the balanced overall (net) cell reaction?


A) 2H+(aq) + 2Ag+(aq) \rarr H2(g) + 2Ag(s)
B) H2(g) + 2Ag(s) \rarr H+(aq) + 2Ag+(aq)
C) 2H+(aq) + 2Ag(s) \rarr H2(g) + 2Ag+(aq)
D) H2(g) + Ag+(aq) \rarr H+(aq) + Ag(s)
E) H2(g) + 2Ag+(aq) \rarr 2H+(aq) + 2Ag(s)

F) B) and E)
G) None of the above

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Which one of the following reagents is capable of transforming Br- (aq) to Br2(l) under standard-state conditions?


A) I- (aq)
B) NO3- (aq)
C) Ag+ (aq)
D) Al3+ (aq)
E) Au3+ (aq)

F) B) and E)
G) All of the above

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Given the following standard reduction potentials in acid solution O2 + 4H+ + 4e- \rarr 2H2O E° = +1.23 V Sn4+ + 2e- \rarr Sn2+ E° = +0.13 V Zn2+ + 2e- \rarr Zn(s)E° = -0.76 V write the formula of the strongest oxidizing agent.

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Using a table of standard reduction potentials, determine which of these reactions (if any) is/are nonspontaneous in the direction indicated at 25°C.


A) 2Fe3+ + 2Cl- \rarr 2Fe2+ + Cl2(g)
B) 2Fe3+ + 2Br- \rarr 2Fe2+ + Br2(l)
C) 2Fe3+ + 2I- \rarr 2Fe2+ + I2(s)
D) A and B
E) All are spontaneous.

F) C) and E)
G) A) and C)

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Consider the following standard reduction potentials in acid solution: Consider the following standard reduction potentials in acid solution:   Which is the weakest oxidizing agent in this list? A) Al<sup>3+</sup>(aq)  B) Al(s)  C) I<sup>-</sup>(aq)  D) I<sub>2</sub>(s)  E) Sn<sup>4+</sup>(aq) Which is the weakest oxidizing agent in this list?


A) Al3+(aq)
B) Al(s)
C) I-(aq)
D) I2(s)
E) Sn4+(aq)

F) B) and C)
G) B) and E)

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Determine the equilibrium constant, Keq, at 25°C for the reaction 2Br- (aq) + I2(s) \rarr Br2(l) + 2I- (aq)


A) 5.7 * 10-19
B) 18.30
C) 1.7 * 1054
D) 1.9 * 1018
E) 5.7 * 10-55

F) D) and E)
G) B) and E)

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Calculate the cell emf for the following reaction at 25°C: 2Ag+(0.010 M)+ H2(1 atm) \rarr 2Ag(s)+ 2H+(pH = 6.0)

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Complete and balance the following redox equation. What is the coefficient of H2O when the equation is balanced using the set of smallest whole-number coefficients? MnO4- + SO32- \rarr Mn2+ + SO42- (acidic solution)


A) 3
B) 4
C) 5
D) 8
E) None of these.

F) A) and E)
G) B) and C)

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Will H2(g)form when Fe is placed in 1.0 M HCl?

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A certain electrochemical cell has for its cell reaction: Zn + HgO \rarr ZnO + Hg Which is the half-reaction occurring at the anode?


A) HgO + 2e- \rarr Hg + O2-
B) Zn2+ + 2e- \rarr Zn
C) Zn \rarr Zn2+ + 2e-
D) ZnO + 2e- \rarr Zn

E) All of the above
F) B) and C)

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