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Which of these aqueous solutions has the highest pH?


A) 0.100 M NaOH
B) 0.100 M Na2O
C) 0.100 M Na3N
D) all of these solutions have the same pH due to the leveling effect
E) these all are solutions of weak bases, so Kb values are needed in order to decide

F) A) and D)
G) None of the above

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Why is it especially dangerous to mix cyanide salts with acids? Write a chemical equation to illustrate your answer.

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The cyanide ion reacts with acid to form hydrogen cyanide, a very weak acid that comes out of solution as a gas.Inhaled in even very small amounts it can rapidly cause death (the cyanide ion bonds essentially irreversibly to Fe(III)in cytochrome oxidase, an important enzyme in metabolism). NaCN(s)+ HCl(aq)\(\to\) HCN(aq)+ NaCl(aq), followed by HCN(aq)\(\to\) HCN(g) or combining these reactions NaCN(s)+ HCl(aq)\(\to\) HCN(g)+ NaCl(aq) (answers will vary depending on salt and acid used in the equation)

Which of these substances is the active ingredient in ordinary household bleach?


A) HCl
B) Cl2
C) NaCl
D) NaClO
E) NaClO4

F) C) and D)
G) A) and D)

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The bond energy of F2 is anomalously low, in comparison with the other halogens, due to the small size of the fluorine atom. Which of the following periodic properties is also anomalously low in the case of fluorine?


A) first ionization energy
B) electron affinity
C) electronegativity
D) diatomic bond length
E) ionic radius

F) A) and B)
G) C) and D)

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The Ostwald process is the main method for the manufacture of nitric acid. In the first step of this process


A) nitrogen and hydrogen react to form NH3.
B) ammonia is burned in O2 to generate N2 and H2O.
C) nitrogen and oxygen react to form NO2.
D) nitrogen and oxygen react to form NO.
E) ammonia is burned with O2 to generate NO and H2O.

F) D) and E)
G) C) and E)

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Which of these aqueous solutions has the lowest pH?


A) 0.100 M NaOH
B) 0.100 M Na2O
C) 0.100 M Na3N
D) all of these solutions have the same pH due to the leveling effect
E) these all are solutions of weak bases, so Kb values are needed in order to decide

F) C) and E)
G) All of the above

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Hydrogen plays an important role in many industrial processes. Write a balanced chemical equation for its production by the water gas reaction.

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C(s)+ H2O(g)\(\to\)CO(g)+ H2(g)

A chemical formula of the carbide ion is


A) Si4-
B) C2-
C) C22-
D) CN-
E) C3-

F) B) and D)
G) B) and C)

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Write the chemical formula of the oxide ion.

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Ozone (O3) and oxygen gas (O2) are examples of


A) isotopes.
B) allotropes.
C) polymorphs.
D) alloys.
E) amphoterism.

F) A) and E)
G) A) and D)

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The main commercial source of bromine is


A) silver bromide ore.
B) seawater.
C) the Frasch process.
D) phosphate rock.
E) the Ostwald process.

F) B) and D)
G) All of the above

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Write the formula for the binary hydride you would expect calcium to form.

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Which of these substances is being considered as a replacement fuel for gasoline?


A) D2O
B) H2
C) NO2
D) F2
E) He

F) B) and E)
G) A) and D)

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The term catenation describes the


A) tendency of carbon atoms to form cations in the presence of alkali metals.
B) process of creating synthetic gas from coal.
C) extraction of precious metals with sodium or potassium cyanide.
D) ability of carbon atoms to form long chains and rings.
E) interaction of Group 4A elements with Group 8A elements at high pressures and temperatures to form coordination compounds.

F) All of the above
G) B) and E)

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P4O6 and P4O10 are allotropes of phosphorus.

A) True
B) False

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Write the chemical formula of the superoxide ion.

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O2-

The presence of ozone in the upper atmosphere is important because


A) O3 absorbs outgoing radiation from the earth's surface, thus helping to keep the earth warm.
B) O3 absorbs harmful solar radiation.
C) O3 dissolves in water droplets and is very reactive.
D) O3 is a major reactant in photosynthesis.

E) B) and C)
F) None of the above

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Which one of these elements is a liquid at room temperature?


A) bromine
B) chlorine
C) fluorine
D) iodine
E) selenium

F) B) and E)
G) A) and B)

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Which one of these elements is not a gas at room temperature?


A) chlorine
B) fluorine
C) nitrogen
D) oxygen
E) sulfur

F) A) and B)
G) B) and D)

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Write a balanced chemical equation to show the production of chlorine by the chlor-alkali process.

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