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Consider the oxides XO2,where X is one of the first 20 elements.Identify X in each of the following cases: a.XO2 is a natural component of the atmosphere,whose buildup is implicated in climate change. b.XO2 is a toxic,brown gas which is a serious air pollutant. c.XO2 is a colorless,toxic gas formed during the combustion of coal. d.XO2 is network solid;the element X itself is also a network solid.

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In the gas phase,AlCl3 exists as molecules of Al2Cl6.

A) True
B) False

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Predict the products for the following set of reactants. Li(s) + CH3Cl(g) \to


A) CH3CH3(g) + LiCl(s)
B) CH4(g) + LiCl(s)
C) CH3Li(s) + LiCl(s)
D) CH3Li(s) + Cl2(g)
E) CH2Li(s) + HCl(g)

F) A) and B)
G) D) and E)

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Which of the following oxides will be the most acidic?


A) Al2O3
B) Ga2O3
C) In2O3
D) Tl2O3
E) None of these oxides is acidic.

F) C) and E)
G) A) and C)

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Predict the products for the reaction of the following set of reactants. Mg(s) + Cl2(g) \to


A) MgCl(s)
B) MgCl2(s)
C) MgCl(l)
D) MgCl2(l)
E) MgCl2(aq)

F) A) and B)
G) A) and C)

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What are the products of the reaction of potassium hydride and water? KH(s) + H2O(l) \to


A) K(s) + H2(g) + OH-(aq)
B) K(s) + H2(g) + O2(g)
C) KOH(s) + O2(g)
D) K+(aq) + H2(g) + O2(g)
E) K+(aq) + H2(g) + OH-(aq)

F) C) and E)
G) A) and D)

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Sulfuric acid is produced when sulfur dioxide dissolves in water.

A) True
B) False

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Thallium can form two oxides,Tl2O and Tl2O3.Which will be the more basic substance?


A) Tl2O
B) Tl2O3
C) They have the same strength as bases.
D) Neither compound has any acidic or basic properties.
E) More information is needed to make an accurate prediction.

F) B) and E)
G) D) and E)

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Predict the products for the following set of reactants. PCl3(l) + H2O(l) \to


A) H3PO3(aq) + HCl(aq)
B) H3PO4(aq) + Cl2(g)
C) PH3(g) + HCl(aq) + O2(g)
D) P2O5(s) + HCl(aq)
E) PCl5(l) + PH3(g) + O2(g)

F) A) and B)
G) D) and E)

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Write balanced equations,showing all reactants and products,to represent a.the reaction of lithium metal with oxygen to form lithium oxide. b.the formation of ammonia in the Haber process.

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a.4Li(s)+ O2(g) blured image 2L...

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Unlike the remainder of the Group 1A(1) elements,lithium forms many salts that have some covalent bond character.What is a reason for this behavior?


A) The high first ionization energy of lithium makes sharing the electron easier than transferring it.
B) The high charge density on the lithium cation deforms nearby polarizable electron clouds.
C) The atomic radius of lithium enables it to share its valence electron effectively.
D) Since lithium has only 1 electron in its 2s orbital,it can accept an electron from another element.
E) Lithium's electronegativity is more like that of a non-metal than a metal.

F) A) and D)
G) B) and E)

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The elements from Groups 1A(1) and 2A(2) are


A) strong acids.
B) strong bases.
C) amphoteric.
D) strong oxidizing agents.
E) strong reducing agents.

F) D) and E)
G) A) and D)

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Boron has 3 valence electrons.Which of the following processes is involved in boron's achieving a complete outer shell?


A) formation of a B3+ cation
B) formation of bridge bonds
C) formation of π\pi -bonds using its d-orbitals
D) formation of π\pi -bonds using sp3-orbitals
E) None of these choices is correct.

F) A) and E)
G) All of the above

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Most of the alkali metal salts are soluble in water while many alkaline earth salts have very low solubilities.Why is this so?


A) The alkali metal cations are smaller than the alkaline earth cations and are more easily hydrated.
B) The alkali metals have lower ionization energies than alkaline earth elements.
C) The alkaline earth salts have much greater lattice energies than the alkali metal salts.
D) The alkaline earth metals have greater heats of atomization than the alkali metals.
E) Alkaline earth cations have very low heats of hydration.

F) B) and D)
G) C) and D)

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Predict the products for the following set of reactants. Ca3As2(s) + H2O(l) \to


A) As3+(aq) + Ca(OH) 2(aq)
B) As(OH) 3(s) + Ca2+(aq) + H2(g)
C) As(OH) 3(s) + Ca(OH) 2(aq)
D) AsH3(g) + Ca(OH) 2(aq)
E) CaH2(aq) + As2O3(aq)

F) None of the above
G) A) and B)

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Predict the products for the reaction of the following set of reactants. CaO(s) + H2O(l) \to


A) Ca2+(aq) + OH-(aq) + H2(g)
B) Ca2+(aq) + H2(g) + O2(g)
C) Ca2+(aq) + H3O+(aq)
D) Ca(OH) 2(s)
E) CaH2(s) + O2(g)

F) All of the above
G) A) and D)

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Potassium is a strong reducing agent.

A) True
B) False

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Which of the following has the most allotropes?


A) carbon
B) sulfur
C) oxygen
D) selenium
E) nitrogen

F) C) and D)
G) A) and E)

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Predict the products for the reaction of the following set of reactants. MgCO3(s) + heat \to


A) Mg(s) + CO(g)
B) Mg(s) + CO2(g)
C) MgO(s) + CO(g)
D) MgO(s) + CO2(g)
E) no reaction

F) A) and D)
G) B) and E)

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Dinitrogen monoxide,N2O,is


A) a brown poisonous gas that is one of the chemicals involved in the production of photochemical smog.
B) a colorless gas used in the production of nitric acid.
C) a colorless gas used as an aerosol propellant.
D) a colorless gas that disproportionates into nitrogen and oxygen.
E) None of these choices is correct.

F) B) and E)
G) A) and D)

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